CobaltMaghrebV1, Main, Exploration, bibRecord, 000384

Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

Identifieur interne : 000384 ( Main/Exploration ); précédent : 000383; suivant : 000385

Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

Auteurs : Hicham Gueddar [Maroc] ; Rachid Bouhfid [Maroc] ; El Mokhtar Essassi [Maroc] ; Nabil El Brahmi [Maroc, France] ; Lahcen El Ammari [Maroc]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3588380

Abstract

In the title compound, [CoCl₂(C₁₇H₁₃N₃S)₂], the Co^II atom exhibits a distorted octahedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands. The two chelate rings including the Co^II atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thiazole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole molecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588380

DOI: 10.1107/S1600536812048751
PubMed: 23476345
PubMed Central: 3588380

Affiliations:

France, Maroc

Le document en format XML

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<italic>N</italic>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, [CoCl<sub>2</sub>
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], the Co<sup>II</sup>
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-benzimidazole ligands. The two chelate rings including the Co<sup>II</sup>
 atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thiazole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole molecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

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Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

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Abstract

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Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)

Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)